Arginine as a multifunctional additive for high performance S‐cathode

Advancement of sulfur (S) cathode of lithium–sulfur (Li–S) batteries is hindered by issues such as insulating nature of sulfur, sluggish redox kinetics, polysulfide dissolution and shuttling. To address these issues, we initiate a study on applying an important amino acid of protein, arginine (Arg), as a functional additive into S cathodes. Based on our simulation study, the positively charged Arg facilitates strong interactions with polysulfides. The experimental results indicate that the interaction enable capability of trapping polysulfides within the S cathode, responsible for reducing shuttle effects. Furthermore, the positively charged Arg also promotes efficient ion diffusion and polysulfides conversion. The new findings include that, with addition of only 1 wt% Arg, the resultant cathode demonstrates effectively enhanced electrolyte wettability, polysulfide adsorption and redox kinetics, leading to enhanced rate performance and long‐term cycling stability. This study highlights the great potential of amino acids being able to act as effective functional bio‐additives in S cathode, paving a new way to high‐performance and sustainable energy storage solutions.