Metal-free, visible-light driven α-C(sp<sup>3</sup>)–H <i>gem</i>-difluoroallylation of glycine derivatives with trifluoromethyl alkenes and 1,3-enynes

doi:10.1039/d3gc01750h

DOI: 10.1039/d3gc01750h ISSN: 1463-9262

Metal-free, visible-light driven α-C(sp³)–H gem-difluoroallylation of glycine derivatives with trifluoromethyl alkenes and 1,3-enynes

Zi-Hang Yuan, Hong Xin, Lu Zhang, Pin Gao, Xu Yang, Xin-Hua Duan, Li-Na Guo

Pollution
Environmental Chemistry

A metal free, visible-light driven α-C(sp³)−H gem-difluoroallylation of glycine derivatives with CF₃-alkenes and 1,3-enynes is presented under redox-neutral conditions with good yields and excellent functional group compatibility.

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Metal-free, visible-light driven α-C(sp3)–H gem-difluoroallylation of glycine derivatives with trifluoromethyl alkenes and 1,3-enynes

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Metal-free, visible-light driven α-C(sp³)–H gem-difluoroallylation of glycine derivatives with trifluoromethyl alkenes and 1,3-enynes