Temperature‐Dependent Operando Raman Analysis of a WO₃‐Based Metal‐Oxide Gas Sensor Detecting Triacetone Triperoxide

In this work, the surface reactions of the homemade explosive triacetone triperoxide on tungsten oxide (WO₃) sensor surfaces are studied to obtain detailed information about the chemical reactions taking place. Semiconductor gas sensors based on WO₃ nanopowders are therefore produced and characterized by scanning electron microscopy, X‐ray diffraction, and Raman spectroscopy. To analyze the reaction mechanisms at the sensor surface, the sensor is monitored online under operation conditions using Raman spectroscopy, which allows to identify the temperature‐dependent sensor reactions. By combining information from the Raman spectra with data on the changing resistivity of the underlying semiconductor, it is possible to establish a correlation between the adsorbed gas species and the physical properties of the WO₃ layer. In the results, it is indicated that a Lewis acid–base reaction is the most likely mechanism for the increase in resistance observed at temperatures below 150 °C. In the results, at higher temperatures, the assumption of a radical mechanism that causes a decrease in resistance is supported.