DOI: 10.1039/d3dt04322c ISSN: 1477-9226
Thermodynamics of the Eu(iii )–Mg–SO4–H2O and Eu(iii )–Na–SO4–H2O systems. Part I: solubility experiments and the full dissociation Pitzer model
P. F. dos Santos, A. Lassin, X. Gaona, K. Garbev, M. Altmaier, B. Madé - Inorganic Chemistry
A thermodynamic description of complex sulfate systems of relevance for nuclear waste disposal is provided. A full dissociation Pitzer model is derived for the system Eu(
iii
)–Mg/Na–SO4–H2O based on solubility experiments and comprehensive solid phase characterization.