Towards Ultrahigh Rate and Cycling Performance of Cathode Materials of Sodium Ion Battery by Introducing a Bicontinuous Porous Structure

Abstract

The emerging sodium‐ion batteries (SIBs) are one of the most promising candidates expected to complement lithium‐ion batteries (LIBs) and diversify the battery market. However, the exploitation of cathode materials with high‐rate performance and long‐cycle stability for SIBs has remained one of the major challenges. To this end, we demonstrated an efficient approach to enhance rate and cycling performance by introducing an ordered bicontinuous porous structure into cathode materials of SIBs. Prussian blue analogues (PBAs) were selected because they are recognized as a type of most promising SIB cathode materials. Thanks to the presence of 3D continuous channels enabling fast Na⁺ ions diffusion as well as the intrinsic mechanical stability of bicontinuous architecture, the resultant PBAs exhibited excellent rate capability (80 mAh g⁻¹ at 2.5 A g⁻¹) and ultra‐long cycling life (> 3000 circulations at 0.5 A g⁻¹), reaching the top performance of the reported PBA‐based cathode materials. This study opens a new avenue for boosting sluggish ion diffusion kinetics in electrodes of rechargeable batteries, and also provides a new paradigm for solving the dilemma that electrodes’ failure due to high‐stress concentration upon ion storage.

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